Freeze the dynamicity: charge transfer complexation assisted control over the reaction pathway
نویسندگان
چکیده
منابع مشابه
Application of Charge Transfer Complexation Reaction for the Spectroscopy Determination of Anticonvulsant Drug Primidone
The interaction of the perimidone drug in solution state with the σ-acceptor iodine, the aliphatic π-acceptor tetracyanoethylene (TCNE) and the aromatic π-acceptor 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) have been studied through the initial formation of ionic intermediate to charge transfer (CT) complex in methanol at room temperature. The spectral studies of the complexes were determi...
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m 0 7 r m a d s a t p f t u 4,4*-Diphenyltetrathiafulvalene (DPTTF) capped gold nanoarticles of 3to 5-nm diameter have been prepared and their hermal stability has been investigated by variable temperature T–IR spectroscopy. The DPTTF molecules at the cluster surface ndergo charge-transfer complexation with C60 to form Au/ PTTF.C60. Direct evidence of complexation is observed in the -ray photoe...
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Synthetic polymers typically adopt a random-coil conformation in solution primarily driven by the tendency to maximize entropy. Generation of well-defined secondary structures in synthetic polymers, therefore, will need to include specific intrachain intersegment interactions that will provide adequate enthalpic contribution to overcome this entropic penalty associated with the formation of wel...
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This is the first report on use of two visible spectrophotometric methods for the determination of bupropion hydrochloride (BUPH) in pharmaceuticals and spiked human urine. Bupropion is a second-generation antidepressant agent which is also used in the management of smoking cessation. The methods are based on charge transfer complexation reaction of bupropion base (BUP) as n-electron donor with...
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Naphthalene diimides (NDIs) form emissive ground-state charge-transfer (CT) complexes with various electron rich aromatic solvents like benzene, o-xylene and mesitylene. TD-DFT calculation of the complexes suggests CT interaction and accounts for the observed ground-state changes.
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ژورنال
عنوان ژورنال: Chemical Science
سال: 2019
ISSN: 2041-6520,2041-6539
DOI: 10.1039/c9sc03417j